Version 1.5
    Regulation (EC) No 1907/2006

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    1 - Product and Company Information

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    Product Name        TETRAETHYLDIALUMINOXANE, 1.0M SOLUTION    
    I N TOLUENE

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    2 - Hazards Identification

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    SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
    Reacts violently with water. Spontaneously flammable in air. Toxic
    by inhalation, in contact with skin and if swallowed.

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    3 - Composition/Information on Ingredients

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    Product Name        CAS #        EC no        Annex I    
    Index Number
    TETRAETHYLDIALUMINOXANE, 1.0M        1069-83-6 None        None    
    SOLUTION INTOLUENE
    Formula        C8H20Al2O    
    Molecular Weight 186,2100 AMU

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    4 - First Aid Measures

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    AFTER INHALATION
    If inhaled, remove to fresh air. If not breathing give
    artificial respiration. If breathing is difficult, give oxygen.
    AFTER INGESTION
    If swallowed, wash out mouth with water provided person is
    conscious. Call a physician.

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    5 - Fire Fighting Measures

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    CONDITIONS OF FLAMMABILITY
    Catches fire if exposed to air.
    EXTINGUISHING MEDIA
    Suitable: Carbon dioxide, dry chemical powder, or appropriate
    foam.
    Unsuitable: Do not use water.
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    SPECIAL RISKS
    Specific Hazard(s): Pyrophoric material. Vapor may travel
    considerable distance to source of ignition and flash back.
    Emits toxic fumes under fire conditions.
    Explosion Hazards: Vapor may travel considerable distance to
    source of ignition and flash back. Container explosion may occur
    under fire conditions.
    SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
    Wear self-contained breathing apparatus and protective clothing
    to prevent contact with skin and eyes.
    SPECIFIC METHOD(S) OF FIRE FIGHTING
    Use water spray to cool fire-exposed containers.

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    6 - Accidental Release Measures

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    PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
    Evacuate area. Shut off all sources of ignition.
    PROCEDURE(S) OF PERSONAL PRECAUTION(S)
    Wear self-contained breathing apparatus, rubber boots, and heavy
    rubber gloves.
    METHODS FOR CLEANING UP
    Cover with an activated carbon adsorbent, take up and place in
    closed containers. Transport outdoors. Ventilate area and wash
    spill site after material pickup is complete.

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    7 - Handling and Storage

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    HANDLING
    Directions for Safe Handling: Do not breathe vapor. Do not get
    in eyes, on skin, on clothing. Avoid prolonged or repeated
    exposure.
    STORAGE
    Conditions of Storage: Keep tightly closed. Store in a cool dry
    place.
    Incompatible Materials: Do not allow contact with water

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    8 - Exposure Controls / Personal Protection

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    ENGINEERING CONTROLS
    Safety shower and eye bath. Use only in a chemical fume hood.
    GENERAL HYGIENE MEASURES
    Wash thoroughly after handling. Wash contaminated clothing before
    reuse.
    PERSONAL PROTECTIVE EQUIPMENT
    Special Protective Measures: Wear appropriate government approved
    respirator, chemical-resistant gloves, safety goggles, other
    protective clothing.

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    9 - Physical and Chemical Properties

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    pH N/A
    BP/BP Range        111,000 °C    
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    MP/MP Range        N/A    
    Flash Point        N/A    
    Flammability        N/A    
    Autoignition Temp        N/A    
    Oxidizing Properties N/A
    Explosive Properties N/A
    Explosion Limits        N/A    
    Vapor Pressure        N/A    
    SG/Density        0,8600 g/cm3    
    Partition Coefficient N/A
    Viscosity        N/A    
    Vapor Density        N/A    
    Saturated Vapor Conc. N/A
    Evaporation Rate        N/A    
    Bulk Density        N/A    
    Decomposition Temp.        N/A    
    Solvent Content        N/A    
    Water Content        N/A    
    Surface Tension        N/A    
    Conductivity        N/A    
    Miscellaneous Data        N/A    
    Solubility        N/A    

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    10 - Stability and Reactivity

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    STABILITY
    Conditions of Instability: Air.
    Reactions to Avoid: Reacts violently with:
    Materials to Avoid: Oxidizing agents, Water.
    HAZARDOUS DECOMPOSITION PRODUCTS
    Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide,
    Aluminum, Aluminum oxide.

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    11 - Toxicological Information

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    SIGNS AND SYMPTOMS OF EXPOSURE
    Exposure to and/or consumption of alcohol may increase toxic
    effects. Inhalation studies on toluene have demonstrated the
    development of inflammatory and ulcerous lesions of the penis,
    prepuce, and scrotum in animals. Lung irritation, chest pain,
    and edema which may be fatal. Exposure can cause: Symptoms of
    exposure may include burning sensation, coughing, wheezing,
    laryngitis, shortness of breath, headache, nausea, and vomiting.
    ROUTE OF EXPOSURE
    Multiple Routes: High concentrations are extremely destructive
    to tissues of the mucous membranes and upper respiratory tract,
    eyes, and skin. Harmful if swallowed, inhaled, or absorbed
    through skin.
    TARGET ORGAN INFORMATION
    Bladder. Kidneys. Liver. Brain.
    CONDITIONS AGGRAVATED BY EXPOSURE
    May cause nervous system disturbances.

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    12 - Ecological Information

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    No data available.
    ALDRICH        www.molbase.com    

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    13 - Disposal Considerations

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    SUBSTANCE DISPOSAL
    Burn in a chemical incinerator equipped with an afterburner and
    scrubber but exert extra care in igniting as this material is
    highly flammable. Observe all federal, state, and local
    environmental regulations.

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    14 - Transport Information

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    RID/ADR
    UN#: 3394
    Class: 4.2
    PG: I
    Subrisk: 4.3
    Proper Shipping Name: Organometallic substance,
    liquid, pyrophoric, water-reactive
    IMDG
    UN#: 3394
    Class: 4.2
    PG: I
    Subrisk: 4.3
    Proper Shipping Name: Organometallic substance,
    liquid, pyrophoric, water-reactive
    Marine Pollutant: No
    Severe Marine Pollutant: No
    Technical Name: Required
    IATA
    UN#: 3394
    Class: 4.2
    PG: I
    Subrisk: 4.3
    Proper Shipping Name: Organometallic substance,
    liquid, pyrophoric, water-reactive
    Inhalation Packing Group I: No
    Technical Name: Required

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    15 - Regulatory Information

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    CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
    INDICATION OF DANGER: F-T
    Highly Flammable. Toxic.
    R-PHRASES: 14-17-23/24/25
    Reacts violently with water. Spontaneously flammable in air.
    Toxic by inhalation, in contact with skin and if swallowed.
    S-PHRASES: 16-26-28-36/37/39-45
    Keep away from sources of ignition - no smoking. In case of
    contact with eyes, rinse immediately with plenty of water and
    seek medical advice. After contact with skin, wash immediately
    with plenty of water. Wear suitable protective clothing,
    gloves, and eye/face protection. In case of accident or if you
    feel unwell, seek medical advice immediately (show the label
    where possible).
    Caution: Substance not yet fully tested (EU).

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    16 - Other Information
    ALDRICH        www.molbase.com    

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    WARRANTY
    The above information is believed to be correct but does not
    purport to be all inclusive and shall be used only as a guide. The
    information in this document is based on the present state of our
    knowledge and is applicable to the product with regard to
    appropriate safety precautions. It does not represent any
    guarantee of the properties of the product. Inc.,
    shall not be held liable for any damage resulting from handling or
    from contact with the above product. See reverse side of invoice
    or packing slip for additional terms and conditions of sale.
    Copyright 2010 Co. License granted to make
    unlimitedpaper copies for internal use only.
    DISCLAIMER
    For R&D use only. Not for drug, household or other uses.
    ALDRICH        www.molbase.com    

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SECTION 16 - ADDITIONAL INFORMATION
N/A