2,4,5,7-四硝基-9-芴酮

2,4,5,7-四硝基-9-芴酮 基本信息
CAS号 746-53-2 分子式 C13H4N4O9
分子量 360.19200 精确质量  359.99800
PSA  200.35000 LogP  4.62360

基本信息 展开↓

CAS号:
746-53-2
3D弹球模型:
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分子式:
C13H4N4O9
分子量:
360.19200
中文名称:
2,4,5,7-四硝基-9-芴酮
英文名称:
2,4,5,7-tetranitrofluoren-9-one
中文别名:
2,4,5,7-四硝基-9-芴酮
英文别名:
2,4,5,7-tetranitrofluoren-9-one;
9H-Fluoren-9-one,2,4,5,7-tetranitro;
2,4,5,7-Tetranitro-9H-fluoren-9-one;
2,4,5,7-tetranitro-fluoren-9-one;
2,4,5,7-Tetranitro-fluoren-9-on;
Fluoren-9-one,2,4,5,7-tetranitro;
Tetranitrofluorenone;
9H-Fluoren-9-one,tetranitro;
2,4,5,7-Tetranitrofluorenone;
2,4,5,7-Tetranitro-9-fluorenone
精确分子量/精确质量:
359.99800
极性分子表面积/PSA:
200.35000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
EINECS:
212-018-8
InChI:
The Key: JOERSAVCLPYNIZ-UHFFFAOYSA-N

物化性质展开↓

密度:
1.874g/cm3
熔点:
251-253ºC
沸点:
616.2ºC at760mmHg
闪点:
318.4ºC
折射率:
1.773

安全信息展开↓

风险类别:
1.1

合成路线查看所有的合成路线

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    9-芴酮

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    2,4,5,7-四硝基-9-芴酮

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    2,4,5,7-四硝基-9-芴酮

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    2,4,5,7-四硝基-9-芴酮

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毒理性展开↓

CHEMICAL IDENTIFICATION

RTECS NUMBER :
LL9095200
CHEMICAL NAME :
9H-Fluoren-9-one, 2,4,5,7-tetranitro-
CAS REGISTRY NUMBER :
746-53-2
BEILSTEIN REFERENCE NO. :
1896718
LAST UPDATED :
199710
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C13-H4-N4-O9
MOLECULAR WEIGHT :
360.21

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :
Mutation test systems - not otherwise specified
TEST SYSTEM :
Bacteria - Escherichia coli
DOSE/DURATION :
1250 ng/tube
REFERENCE :
EMMUEG Environmental and Molecular Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.10- 1987- Volume(issue)/page/year: 18,41,1991

MSDS 展开↓

Name: 2 4 5 7-Tetranitro-9-Fluorenone 98% Material Safety Data Sheet
Synonym: Fluoren-9-One, 2,4,5,7-Tetranitro-
CAS: 746-53-2
Section 1 - Chemical Product   MSDS Name:2 4 5 7-Tetranitro-9-Fluorenone 98% Material Safety Data Sheet
Synonym:Fluoren-9-One, 2,4,5,7-Tetranitro-

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
746-53-2 2,4,5,7-Tetranitro-9-Fluorenone 98% 212-018-8
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use agent most appropriate to extinguish fire.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.
Exposure Limits CAS# 746-53-2: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Powder
Color: light brown
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 251.00 - 253.00 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C13H4N4O9
Molecular Weight: 360.20

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 746-53-2: LL9095200 LD50/LC50:
Not available.
Carcinogenicity:
2,4,5,7-Tetranitro-9-Fluorenone - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 746-53-2: No information available.
Canada
CAS# 746-53-2 is listed on Canada's NDSL List.
CAS# 746-53-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 746-53-2 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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