双(2,4,5-三氯苯基)二硫化物

双(2,4,5-三氯苯基)二硫化物 基本信息
CAS号 3808-87-5 分子式 C12H4Cl6S2
分子量 425.00800 精确质量  421.78900
PSA  50.60000 LogP  8.40640

基本信息 展开↓

CAS号:
3808-87-5
3D弹球模型:
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分子式:
C12H4Cl6S2
分子量:
425.00800
中文名称:
双(2,4,5-三氯苯基)二硫化物
英文名称:
Bis(2,4,5-trichlorophenyl) Disulfide
中文别名:
双(2,4,5-三氯苯基)二硫化物;
2,4,5-三氯苯基二硫醚;
双(2,4,5-三氯苯基)二硫醚;
双(2,4,6-三氯苯基)二硫化物;
二(2,4,5-三氯苯基)二硫醚;
二(2,4,5-三氯苯)二硫醚
英文别名:
Bis(2,4,5-trichlorophenyl) Disulfide;
1,2,4-trichloro-5-[(2,4,5-trichlorophenyl)disulfanyl]benzene;
Di(2,4,5-trichlorophenyl) Disulfide;
2,4,5-Trichlorophenyl Disulfide
精确分子量/精确质量:
421.78900
极性分子表面积/PSA:
50.60000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
EINECS:
223-279-2
InChI:
The Key: ZUVJVEOHQKNMPN-UHFFFAOYSA-N

生产制备方法及用途展开↓

制备方法


染料和橡胶制备。

用途简介


物化性质展开↓

密度:
1.73g/cm3
熔点:
140-144ºC(lit.)
沸点:
460.9ºC at 760 mmHg
闪点:
213.2ºC
折射率:
1.718

安全信息展开↓

海关代码:
2930909090
安全说明:
S24/25

合成路线查看所有的合成路线

  • 3773-14-6

    2,4,5-三氯苯硫醇

  • ~90%

  • 3808-87-5

    双(2,4,5-三氯苯基)二硫化物

  • 62726-90-3

    2,4,5-trichlorobenzenesulfenyl chloride

  • ~85%

  • 3808-87-5

    双(2,4,5-三氯苯基)二硫化物

  • +

  • 4163-78-4

    2,4,5-三氯硫代苯甲醚

  • 88-67-5

    邻碘苯甲酸

  • +

  • 3773-14-6

    2,4,5-三氯苯硫醇

  • 3808-87-5

    双(2,4,5-三氯苯基)二硫化物

  • +

  • 94923-56-5

    94923-56-5

化学图谱

  1. 双(2,4,5-三氯苯基)二硫红外图谱(IR1)

  2. 双(2,4,5-三氯苯基)二硫红外图谱(IR2)

  3. 双(2,4,5-三氯苯基)二硫质谱(MS)

  4. 双(2,4,5-三氯苯基)二硫核磁图(13CNMR)

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MSDS 展开↓

Name: 2 4 5-Trichlorophenyl Disulfide 98% Material Safety Data Sheet
Synonym: None Known
CAS: 3808-87-5
Section 1 - Chemical Product   MSDS Name:2 4 5-Trichlorophenyl Disulfide 98% Material Safety Data Sheet
Synonym:None Known

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
3808-87-5 2,4,5-Trichlorophenyl Disulfide 98% 223-279-2
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
Use agent most appropriate to extinguish fire.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.
Exposure Limits CAS# 3808-87-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Powder
Color: off-white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 140.00 - 144.00 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C12H4Cl6S2
Molecular Weight: 425.00

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents, reducing agents, strong bases.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, sulfur oxides (SOx), including sulfur oxide and sulfur dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 3808-87-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2,4,5-Trichlorophenyl Disulfide - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 3808-87-5: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 3808-87-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 3808-87-5 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

海关数据查看详细

中国海关编码:2930909090

概述:
2930909090. 其他有机硫化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%
申报要素:
品名, 成分含量, 用途
摘要/Summary:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

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