氯(二甲基)膦

氯(二甲基)膦 基本信息
CAS号 811-62-1 分子式 C2H6ClP
分子量 96.49580 精确质量  95.98960
PSA  13.59000 LogP  1.88170

基本信息 展开↓

CAS号:
811-62-1
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分子式:
C2H6ClP
分子量:
96.49580
中文名称:
氯(二甲基)膦
英文名称:
Chloro(dimethyl)phosphine
中文别名:
氯(二甲基)膦;
二甲基氯化膦;
二甲基氯化磷
英文别名:
Chloro(dimethyl)phosphine;
chloro(dimethyl)phosphane
精确分子量/精确质量:
95.98960
极性分子表面积/PSA:
13.59000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
贝尔斯坦号/MDL:
MFCD00013620
EINECS:
212-372-3
InChI:
InChI=1/C2H6ClP/c1-4(2)3/h1-2H3

物化性质展开↓

外观与性状:
无色至淡黄色液体
密度:
1.22
沸点:
76ºC
闪点:
-18ºC
存储条件/存储方法:
库房低温,通风,干燥,密闭保存
稳定性相关:

常温常压下稳定,避免强氧化剂 热和水分接触

其它信息:

1.       性状:未确定

2.       密度(g/mL,25/4):1,22 g/cm3

3.       相对蒸汽密度(g/mL,空气=1):未确定

4.       熔点(ºC):76-77°C

5.       沸点(ºC,常压):未确定

6.       沸点(ºC,5.2kPa):未确定

7.       折射率:未确定

8.       闪点(ºC):-18°C

9.       比旋光度(º):未确定

10.    自燃点或引燃温度(ºC):未确定

11.    蒸气压(kPa,25ºC):未确定

12.    饱和蒸气压(kPa,60ºC):未确定

13.    燃烧热(KJ/mol):未确定

14.    临界温度(ºC):未确定

15.    临界压力(KPa):未确定

16.    油水(辛醇/水)分配系数的对数值:未确定

17.    爆炸上限(%,V/V):未确定

18.    爆炸下限(%,V/V):未确定

19.    溶解性:未确定

安全信息展开↓

风险类别:
4.2
危险类别码:
R17
安全标志:
S16:远离火源。
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
S45:出现意外或者感到不适,立刻到医生那里寻求帮助(最好带去产品容器标签)。
:

合成路线查看所有的合成路线

  • 3676-91-3

    dimethylphosphanyl(dimethyl)phosphane

  • ~82%

  • 811-62-1

    氯(二甲基)膦

  • 74-87-3

    氯甲烷

  • +

  • 676-83-5

    甲基二氯膦

  • 811-62-1

    氯(二甲基)膦

  • 683-84-1

    (dimethylamino)dimethylphosphine

  • 811-62-1

    氯(二甲基)膦

化学图谱

  1. 二甲基氯化膦核磁图(1HNMR)

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毒理性展开↓

生态数据:

对水是稍微有害的,不要让未稀释或大量的产品接触地下水,水道或者污水系统,若无政府许可,勿将材料排入周围环境

MSDS 展开↓


Section 1: Product Identification
   Chemical Name:       Dimethylchlorophosphine, min. 97%    
   CAS Registry Number:       811-62-1    
   Formula:       (CH3)2PCl    
   EINECS Number:       none    
   Chemical Family:       organophosphine halide    
   Synonym:       none    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       811-62-1       100%       no data       no data    

Section 3: Hazards Identification
   Harmful by inhalation, in contact with skin and if swallowed. Material releases acid fumes. Inhalation of vapors
   Emergency Overview:
   may lead to headache and dizziness. Severe irritant to skin, eyes, and mucous membranes.
   Primary Routes of Exposure:       Ingestion, skin, inhalation    
   Eye Contact:       Causes severe irritation of the eyes.    
   Skin Contact:       Harmful in contact with skin. Causes severe irritation of the skin or thermal burns if ignited.    
   Harmful by inhalation. Inhalation may lead to headaches and dizziness. Causes severe irritation to the nose
   Inhalation:
   and mucous memb
   Ingestion:       Harmful if swallowed. May cause vomiting and diarrhea.    
   Acute Health Affects:       Harmful by inhalation, in contact with skin and if swallowed.    
   Chronic Health Affects:       No information available on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       -1°F    
   Autoignition Temperature:       no data    
   Explosion Limits:       no data    
   Extinguishing Medium:       carbon dioxide, dry powder or foam    
   Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus
   Special Fire Fighting Procedures:
   and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic organic fumes, hydrochloric acid fumes, and vapors of    
   Decomposion Products:       phosphorus pentoxide.    
   Unusual Fire or Explosion Hazards: Spontaneously flammable in air, especially in contact with organic matter such as paper or cloth.

SECTION 6: Accidental Release Measures
   Small spills can be mixed with sodium bicarbonate or other suitable absorbents. Spillage in areas not
   adequately ventilation will require an evacuation of site. Material may spontaneously ignite. Emergency
   Spill and Leak Procedures:
   response teams will require self-contained breathing apparatus. Spill should be absorbed into vermiculite or
   other suitable absorbent.

SECTION 7: Handling and Storage
   Material is shipped in an all glass ampoule. Material must be handled and stored under an inert atmosphere
   Handling and Storage:
   of nitrogen or argon.

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       Material has a pungent odor. Always handle material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Material has a pungent odor. Always handle material in an efficient fume hood.    
   Additional Protection:       Wear a full face shield, flame resistant lab apron and suitable gloves.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       colorless to pale yellow liq.    
   Molecular Weight:       96.50    
   Melting Point:       no data    
   Boiling Point:       76-77°C    
   Vapor Pressure:       no data    
   Specific Gravity:       1.22    
   Odor:       pungent, acidic odor    
   Solubility in Water:       reacts violently with water    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture-sensitive liquid    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       contact with air.    
   Incompatibility:       water, air, oxidizing agents, alcohols, halogens and active metals    
   Decomposition Products:       carbon dioxide, carbon monoxide, hydrogen chloride, organic fumes, and phosphorus pentoxide.    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       No data available    
   Mutagenic Effects:       No data available    
   Tetratogenic Effects:       No data available    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Pyrophoric liquids, Organic, N.O.S.    
   Hazard Class (CFR):       4.2    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       I    
   UN ID Number (CFR):       UN# 2845    
   Shipping Name (IATA):       Forbidden    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       UN# 2845    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Not reportable under SARA Title 313    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

分子结构与计算化学数据展开↓

计算化学数据


1.疏水参数计算参考值(XlogP):0.7

2.氢键供体数量:0

3.氢键受体数量:0

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积0

7.重原子数量:4

8.表面电荷:0

9.复杂度:13.5

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

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    dimethylphosphanyl(dimethyl)phosphane

  • 683-84-1

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