草酸铜

草酸铜 基本信息
CAS号 814-91-5 分子式 C2H2CuO4++
分子量 153.58100 精确质量  152.92500
PSA  74.60000 LogP  -0.84690

基本信息 展开↓

CAS号:
814-91-5
3D弹球模型:
立即前往扯扯看
分子式:
C2H2CuO4++
分子量:
153.58100
中文名称:
草酸铜
英文名称:
Oxalic acid copper(2+) salt (1:1)
中文别名:
草酸铜;
乙二酸铜;
草酸铜(II);
aluminum ethanedioate (2:3);
Acryloyl chloride;
Calcium citrate tribasic;
Calcium citrate;
Calcium Citrate anhydrous;
Phosphoric acid, dimethyl ester;
Dimethyl phosphate;
(14S,17R)-13-ethyl-17-ethynyl-17-hydroxy-1,2,6,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-3H-cyclopenta[a]phenanthren-3-one (non-preferred name);
D(minus)-norgestrel;
Antoxidant 6ppd;
Antioxidant 6PPD (4020);
Antioxidant 6PPD;
N-1,3-dimethylbutyl-N'-phenyl-p-phenylenediamine;
diethyl 2,5-dioxocyclohexane-1,4-dicarboxylate;
O,O-Dimethyl hydrogen dithiophosphate;
O,O-dimethyl hydrogen phosphorodithioate;
copper(2+) bis(O,O-dimethyl phosphorodithioate);
Dimethylphosphorodithioate;
O,O-Dimethyl Dithiophosphate;
h-MG;
Sulfide, 2-chloroethyl ethyl (8CI);
1-chloro-2-(ethylsulfanyl)ethane;
2-chloro ethyl ethyl sulfide;
2-chloroethyl ethyl sulphide
英文别名:
Oxalic acid copper(2+) salt (1:1);
EINECS 233-068-7;
(o-phthalato)copper(II);
copper(II) o-phthalate;
copper oxalate;
Kupfer(II)-oxalat;
copper(2+) phthalate;
Copper phthalate;
copper (II) oxalate
精确分子量/精确质量:
152.92500
极性分子表面积/PSA:
74.60000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
EINECS:
212-411-4
InChI:
InChI=1/C2H2O4.Cu/c3-1(4)2(5)6;/h(H,3,4)(H,5,6);/q;+2

生产制备方法及用途展开↓

制备方法


用作分析试剂,还用于涂料、电子、农药等。

用途简介


物化性质展开↓

外观与性状:
无气味的蓝白色固体
沸点:
365.1ºC at 760 mmHg
闪点:
188.8ºC
水溶解性:
insoluble
存储条件/存储方法:
库房通风低温干燥,防明火,摩擦,火花,与氧化剂分开储运

安全信息展开↓

包装等级:
III
风险类别:
6.1(b)
海关代码:
2917119000
危险类别码:
20/21/22
安全说明:
36
安全标志:
S36:穿戴合适的防护服装。

合成路线查看所有的合成路线

  • 144-62-7

    草酸

  • +

  • 7758-99-8

    硫酸铜,五水

  • 814-91-5

    草酸铜

  • 583-52-8

    草酸二钾

  • +

  • 6046-93-1

    乙酸铜 一水合物

  • 814-91-5

    草酸铜

  • 18324-10-2

    18324-10-2

  • 814-91-5

    草酸铜

毒理性展开↓

CHEMICAL IDENTIFICATION

RTECS NUMBER :
RO2650000
CAS REGISTRY NUMBER :
814-91-5
LAST UPDATED :
199701
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C2-Cu-O4

MSDS 展开↓


Section 1: Product Identification
   Chemical Name:       Copper (II) oxalate hemihydrate    
   CAS Registry Number:       814-91-5    
   Formula:       CuC2O4.0.5H2O    
   EINECS Number:       none    
   Chemical Family:       salt of an organic acid    
   Synonym:       copper oxalate, Oxalic acid, copper salt.    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       814-91-5       100%       1mg/m3 (as Cu)       1mg/m3 (as Cu)    

Section 3: Hazards Identification
   Soluble oxalates are harmful if swallowed. They precipitate calcium from the bloodstream causing violent
   Emergency Overview:
   muscular stimulation, convulsions, collapse, and death.
   Primary Routes of Exposure:       Ingestion, Inhalation of dust.    
   Eye Contact:       May cause moderate to severe irritation of the eyes.    
   Skin Contact:       May cause moderate to severe irritation of the skin.    
   Inhalation:       Dust may be severely irritating to the nose, mucous membranes and respiratory tract.    
   Ingestion:       Ingestion may cause vomiting, pain, violent muscular stimulation, convulsions, collapse, and death.    
   Soluble oxalates remove calcium from the bloodstream. This interferes with the central nervous system
   Acute Health Affects:
   causing violent convulsions and death. Large amounts of copper salts are toxic when ingested.
   Prolonged exposure to oxalates can lead to kidney failure resulting from calcium oxalate precipitation in renal
   Chronic Health Affects:
   tubes. Copper compounds may cause liver and kidney disease.
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with soap and water. Remove contaminated clothes if necessary. Seek medical
   Skin Exposure:
   assistance if irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Antidotes are said to be soluble calcium given orally, and calcium gluconate given intravenously, to be
   Ingestion:
   administered by trained medical personnel. Keep the victim calm. Give the victim water (only if conscious).

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       carbon dioxide, dry powder or foam    
   If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained
   Special Fire Fighting Procedures:
   breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic organic fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Small spills can be mixed with vermiculite or sodium carbonate and swept up.    

SECTION 7: Handling and Storage
   Handling and Storage:       Store in a sealed container. Keep away from heat and moisture.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear appropriate chemical resistant gloves and protective clothing.    
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators
   Respirator:
   requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       blue pwdr.    
   Molecular Weight:       151.57 (160.57)    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       Insoluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable solid    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       Oxidizing agents and active metals    
   Decomposition Products:       Carbon dioxide, carbon monoxide, organic vapors, and metal oxides and carbonates.    

SECTION 11: Toxicological Information
   RTECS Data:       No specific information available on this product.    
   Carcinogenic Effects:       No data available    
   Mutagenic Effects:       No data available    
   Tetratogenic Effects:       No data available    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Listed in the TSCA inventory.    
   SARA (Title 313):       Title compound: See Category Code N100 for reporting.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

海关数据查看详细

中国海关编码:2917119000

概述:
2917119000 其他草酸盐和酯。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0%
申报要素:
品名, 成分含量, 用途, 对苯二甲酸请注明4-CBA值, 对苯二甲酸请注明P-TL酸值, 对苯二甲酸请注明色度, 对苯二甲酸请注明水分
摘要/Summary:
2917119000 oxalic acid salts and esters VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

分子结构与计算化学数据展开↓

计算化学数据


1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:4

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积80.3

7.重原子数量:7

8.表面电荷:0

9.复杂度:60.5

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:2

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