Version 1.6
    Regulation (EC) No 1907/2006

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    1 - Product and Company Information

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    Product Name        ACETIC ACID-UL-14C    

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    2 - Hazards Identification

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    SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
    Flammable. Causes severe burns.

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    3 - Composition/Information on Ingredients

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    Product Name        CAS #        EC no        Annex I    
    Index Number
    ACETIC ACID-1-14C        2845-03-6 None        None    
    Formula        C2H4O2    
    Molecular Weight 60,0500 AMU

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    4 - First Aid Measures

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    AFTER INHALATION
    If inhaled, remove to fresh air. If not breathing give
    artificial respiration. If breathing is difficult, give oxygen.
    AFTER SKIN CONTACT
    In case of skin contact, flush with copious amounts of water for
    at least 15 minutes. Remove contaminated clothing and shoes.
    Call a physician.
    AFTER EYE CONTACT
    In case of contact with eyes, flush with copious amounts of
    water for at least 15 minutes. Assure adequate flushing by
    separating the eyelids with fingers. Call a physician.
    AFTER INGESTION
    If swallowed, wash out mouth with water provided person is
    conscious. Call a physician immediately. Do not induce vomiting.

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    5 - Fire Fighting Measures

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    SIGMA        www.molbase.com    
    EXTINGUISHING MEDIA
    Suitable: For small (incipient) fires, use media such as
    "alcohol" foam, dry chemical, or carbon dioxide. For large
    fires, apply water from as far as possible. Use very large
    quantities (flooding) of water applied as a mist or spray; solid
    streams of water may be ineffective. Cool all affected
    containers with flooding quantities of water.
    SPECIAL RISKS
    Specific Hazard(s): Flammable liquid. Emits toxic fumes under
    fire conditions.
    Explosion Hazards: Vapor may travel considerable distance to
    source of ignition and flash back. Container explosion may occur
    under fire conditions.
    SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
    Wear self-contained breathing apparatus and protective clothing
    to prevent contact with skin and eyes.

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    6 - Accidental Release Measures

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    PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
    Evacuate area. Handle as a radioactive spill.
    PROCEDURE(S) OF PERSONAL PRECAUTION(S)
    Wear self-contained breathing apparatus, rubber boots, and heavy
    rubber gloves.
    METHODS FOR CLEANING UP
    Cover with dry-lime, sand, or soda ash. Place in covered
    containers using non-sparking tools and transport outdoors.
    Ventilate area and wash spill site after material pickup is
    complete.

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    7 - Handling and Storage

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    HANDLING
    Directions for Safe Handling: Do not breathe vapor. Do not get
    in eyes, on skin, on clothing. Avoid prolonged or repeated
    exposure.
    STORAGE
    Conditions of Storage: Keep tightly closed. Keep away from heat,
    sparks, and open flame.
    Store at 2-8°C

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    8 - Exposure Controls / Personal Protection

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    ENGINEERING CONTROLS
    Safety shower and eye bath. Use nonsparking tools. Use only in a
    chemical fume hood.
    GENERAL HYGIENE MEASURES
    Wash contaminated clothing before reuse. Discard contaminated
    shoes. Wash thoroughly after handling.
    PERSONAL PROTECTIVE EQUIPMENT
    Respiratory Protection: Use respirators and components tested and
    approved under appropriate government standards such as NIOSH (US)
    or CEN (EU). Where risk assessment shows air-purifying respirators
    SIGMA        www.molbase.com    
    are appropriate use a full-face respirator with multi-purpose
    combination (US) or type ABEK (EN 14387) respirator cartridges as
    a backup to engineering controls. If the respirator is the sole
    means of protection, use a full-face supplied air respirator.
    Hand Protection: Compatible chemical-resistant gloves.
    Eye Protection: Chemical safety goggles.
    Special Protective Measures: Faceshield (8-inch minimum).

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    9 - Physical and Chemical Properties

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    Appearance        Physical State: Liquid    
    Property        Value        At Temperature or Pressure    
    pH N/A
    BP/BP Range        N/A    
    MP/MP Range        N/A    
    Flash Point        40,000 °C        Method: closed cup    
    Flammability        N/A    
    Autoignition Temp        427,00 °C    
    Oxidizing Properties N/A
    Explosive Properties N/A
    Explosion Limits        Lower: 4,000 %    
    Upper: 16,000 %
    Vapor Pressure        11,400000000 mmHg 20,00 °C    
    Partition Coefficient N/A
    Viscosity        N/A    
    Vapor Density        2,070 g/l    
    Saturated Vapor Conc. N/A
    Evaporation Rate        N/A    
    Bulk Density        N/A    
    Decomposition Temp.        N/A    
    Solvent Content        N/A    
    Water Content        N/A    
    Surface Tension        N/A    
    Conductivity        N/A    
    Miscellaneous Data        N/A    
    Solubility        N/A    

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    10 - Stability and Reactivity

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    STABILITY
    Stable: Stable.
    Conditions to Avoid: Moisture.
    Materials to Avoid: Acids, Bases, Oxidizing agents, Soluble
    carbonates and phosphates, Hydroxides, Oxides, Metals, Acid
    anhydrides, Peroxides, Permanganates, Amines, Alcohols.
    HAZARDOUS DECOMPOSITION PRODUCTS
    Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide.
    HAZARDOUS POLYMERIZATION
    Hazardous Polymerization: Will not occur

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    11 - Toxicological Information

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    SIGNS AND SYMPTOMS OF EXPOSURE
    Ingestion or inhalation of concentrated acetic acid causes
    damage to tissues of the respiratory and digestive tracts.
    Symptoms include: hematemesis, bloody diarrhea, edema and/or
    SIGMA        www.molbase.com    
    perforation of the esophagus and pylorus, hematuria, anuria,
    uremia, albuminuria, hemolysis, convulsions, bronchitis,
    pulmonary edema, pneumonia, cardiovascular collapse, shock, and
    death. Direct contact or exposure to high concentrations of
    vapor with skin or eyes can cause: erythema, blisters, tissue
    destruction with slow healing, skin blackening, hyperkeratosis,
    fissures, corneal erosion, opacification, iritis,
    conjunctivitis, and possible blindness. To the best of our
    knowledge, the chemical, physical, and toxicological properties
    have not been thoroughly investigated. Symptoms of exposure may
    include burning sensation, coughing, wheezing, laryngitis,
    shortness of breath, headache, nausea, and vomiting. Inhalation
    may result in spasm, inflammation and edema of the larynxand
    bronchi, chemical pneumonitis, and pulmonary edema. Material is
    extremely destructive to tissue of the mucous membranes and
    upper respiratory tract, eyes, and skin.
    ROUTE OF EXPOSURE
    Skin Contact: Causes burns.
    Skin Absorption: May be harmful if absorbed through the skin.
    Eye Contact: Causes burns.
    Inhalation: May be harmful if inhaled. Material is extremely
    destructive to the tissue of the mucous membranes and upper
    respiratory tract.
    Ingestion: May be harmful if swallowed.
    TARGET ORGAN INFORMATION
    Teeth. Kidneys.
    CONDITIONS AGGRAVATED BY EXPOSURE
    Severe, acute pancreatitis may occur after ingestion of
    concentrated acetic acid.
    CHRONIC EXPOSURE - CARCINOGEN
    Result: Contains a radioactive isotope which may produce cancer
    and genetic mutation.

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    12 - Ecological Information

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    No data available.

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    13 - Disposal Considerations

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    SUBSTANCE DISPOSAL
    Dispose of spilled material as radioactive waste. Consult local,
    state, and federal regulations on the disposal of radioactive
    waste. Observe all federal, state, and local environmental
    regulations.

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    14 - Transport Information

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    RID/ADR
    UN#: 2910
    Class: 7
    Proper Shipping Name: Radioactive material, excepted
    package, limited quantity of material
    IMDG
    UN#: 2910
    Class: 7
    SIGMA        www.molbase.com    
    Proper Shipping Name: RADIOACTIVE MATERIAL, EXCEPTED
    PACKAGE - LIMITED QUANTITY OF MATERIAL
    Marine Pollutant: No
    Severe Marine Pollutant: No
    IATA
    UN#: 2910
    Class: 7
    Proper Shipping Name: Radioactive material, excepted
    package, limited quantity of material
    Inhalation Packing Group I: No

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    15 - Regulatory Information

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    CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
    INDICATION OF DANGER: R-C
    Radioactive. Corrosive.
    R-PHRASES: 10-35
    Flammable. Causes severe burns.
    S-PHRASES: 16-26-36/37/39-45
    Keep away from sources of ignition - no smoking. In case of
    contact with eyes, rinse immediately with plenty of water and
    seek medical advice. Wear suitable protective clothing, gloves,
    and eye/face protection. In case of accident or if you feel
    unwell, seek medical advice immediately (show the label where
    possible).
    Caution: Substance not yet fully tested (EU).
    COUNTRY SPECIFIC INFORMATION
    Germany
    WGK: 3
    Self-Classification

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    16 - Other Information

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    WARRANTY
    The above information is believed to be correct but does not
    purport to be all inclusive and shall be used only as a guide. The
    information in this document is based on the present state of our
    knowledge and is applicable to the product with regard to
    appropriate safety precautions. It does not represent any
    guarantee of the properties of the product. Inc.,
    shall not be held liable for any damage resulting from handling or
    from contact with the above product. See reverse side of invoice
    or packing slip for additional terms and conditions of sale.
    Copyright 2010 Co. License granted to make
    unlimitedpaper copies for internal use only.
    DISCLAIMER
    For R&D use only. Not for drug, household or other uses.
    SIGMA        www.molbase.com    

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SECTION 16 - ADDITIONAL INFORMATION
N/A