4-甲酰苄基氨基甲酸叔丁酯

4-甲酰苄基氨基甲酸叔丁酯 基本信息
CAS号 156866-52-3 分子式 C13H17NO3
分子量 235.27900 精确质量  235.12100
PSA  55.40000 LogP  2.91470

基本信息 展开↓

CAS号:
156866-52-3
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分子式:
C13H17NO3
分子量:
235.27900
中文名称:
4-甲酰苄基氨基甲酸叔丁酯
英文名称:
TERT-BUTYL N-(4-FORMYLBENZYL)CARBAMATE
中文别名:
4-甲酰苄基氨基甲酸叔丁酯;
N-[(4-甲酰基苯基)甲基]氨基甲酸叔丁酯;
(4-甲酰基苄基)氨基甲酸叔丁酯
英文别名:
TERT-BUTYL N-(4-FORMYLBENZYL)CARBAMATE;
Tert-butylN-[(4-formylphenyl)methyl]carbamate;
tert-butyl 4-formylbenzylcarbamate;
4-(Aminomethyl)benzaldehyde, N-BOC protected;
tert-Butyl N-(4-formylbenzyl)carbamate
精确分子量/精确质量:
235.12100
极性分子表面积/PSA:
55.40000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
InChI:
InChI=1/C13H17NO3/c1-13(2,3)17-12(16)14-8-10-4-6-11(9-15)7-5-10/h4-7,9H,8H2,1-3H3,(H,14,16)

物化性质展开↓

密度:
1.108 g/cm3
熔点:
83ºC
沸点:
389ºC at 760 mmHg
闪点:
189.1ºC
折射率:
1.538
蒸汽压:
0mmHg at 25°C

安全信息展开↓

海关代码:
2924299090

合成路线查看所有的合成路线

  • 875582-80-2

    tert-butyl [4-(1,3-dioxolan-2-yl)benzyl]carbamate

  • ~99%

  • 156866-52-3

    4-甲酰苄基氨基甲酸叔丁酯

  • 123986-64-1

    (4-羟基甲基苄基)-氨基甲酸叔丁酯

  • ~99%

  • 156866-52-3

    4-甲酰苄基氨基甲酸叔丁酯

  • 314732-37-1

    Boc-Amb-N(OMe)Me

  • ~83%

  • 156866-52-3

    4-甲酰苄基氨基甲酸叔丁酯

MSDS 展开↓

Name: tert-Butyl N-(4-formylbenzyl)carbamate Material Safety Data Sheet
Synonym:
CAS: 156866-52-3
Section 1 - Chemical Product   MSDS Name:tert-Butyl N-(4-formylbenzyl)carbamate Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
156866-52-3 tert-Butyl N-(4-formylbenzyl)carbamate 97+% unlisted
Hazard Symbols: XN
Risk Phrases: 22 36/37/38

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
Causes respiratory tract irritation.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
  Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 156866-52-3: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 82.9 - 83.7 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C13H17NO3
Molecular Weight: 235.29

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases, amines.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 156866-52-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
tert-Butyl N-(4-formylbenzyl)carbamate - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 22 Do not breathe dust.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 156866-52-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 156866-52-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 156866-52-3 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

海关数据查看详细

中国海关编码:2924299090

概述:
2924299090. 其他环酰胺(包括环氨基甲酸酯)(包括其衍生物以及他们的盐). 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%
申报要素:
品名, 成分含量, 用途, 包装
摘要/Summary:
2924299090. other cyclic amides (including cyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

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