聚碳化二亚胺

聚碳化二亚胺 基本信息
CAS号 151-51-9 分子式 CH2N2
分子量 42.04000 精确质量  42.02180
PSA  47.70000 LogP  0.51730

基本信息 展开↓

CAS号:
151-51-9
3D弹球模型:
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分子式:
CH2N2
分子量:
42.04000
中文名称:
聚碳化二亚胺
英文名称:
methanediimine
中文别名:
聚碳化二亚胺
英文别名:
methanediimine;
Stabilisator 9000;
carbodiimid;
Polycarbodiimid;
carbodiimine;
Methanediylidenediamine;
polycarbodiimide;
Polycarbodiimide solution;
Methanediimine (9CI);
carbodiimide
精确分子量/精确质量:
42.02180
极性分子表面积/PSA:
47.70000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
贝尔斯坦号/MDL:
MFCD00284329
PubChem:
24869500
InChI:
The Key: VPKDCDLSJZCGKE-UHFFFAOYSA-N

物化性质展开↓

密度:
1.02g/cm3
折射率:
n20/D 1.461
蒸汽压:
14700mmHg at 25°C
存储条件/存储方法:

保持贮藏器密封、储存在阴凉、干燥的地方,确保工作间有良好的通风或排气装置

稳定性相关:

如果遵照规格使用和储存则不会分解,未有已知危险反应

其它信息:

1.         性状:未确定

2.         密度(g/mL,25):1.03

3.         相对蒸汽密度(g/mL,空气=1):未确定

4.         熔点(ºC):未确定

5.         沸点(ºC,常压):154

6.         沸点(ºC,0.67KPa):未确定

7.         折射率:n20/D 1.461

8.         闪点(ºC):46

9.         比旋光度(º):未确定

10.      自燃点或引燃温度(ºC):未确定

11.      蒸气压(mmHg,25ºC):未确定

12.      饱和蒸气压(kPa,20ºC):未确定

13.      燃烧热(KJ/mol):未确定

14.      临界温度(ºC):未确定

15.      临界压力(KPa):未确定

16.      油水(辛醇/水)分配系数的对数值:未确定

17.      爆炸上限(%,V/V):未确定

18.      爆炸下限(%,V/V):未确定

19.      溶解性:未确定

安全信息展开↓

海关代码:
3824909990
危险类别码:
60-10-20/21/22-36/37/38
安全说明:
53-16-26-36/37/39-45
安全标志:
S16:远离火源。
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
S45:出现意外或者感到不适,立刻到医生那里寻求帮助(最好带去产品容器标签)。
S53:避免暴露——使用前先阅读专门的说明。
:
危险标志:
T: Toxic;

合成路线查看所有的合成路线

  • 17220-38-1

    3,4-二氨基呋扎

  • 420-04-2

    单氰胺

  • +

  • 67249-78-9

    aminoisocyanate

  • 288-88-0

    1,2,4-三氮唑

  • 420-04-2

    单氰胺

  • +

  • 24153-51-3

    diazomethane

  • +

  • 151-51-9

    聚碳化二亚胺

  • +

  • 17619-22-6

    ch2=c=nh

  • +

  • 88333-02-2

    Methylene, (methyleneamino)-

  • +

  • 75-05-8

    乙腈

  • 100-97-0

    乌洛托品

  • 34557-54-5

    methane

  • +

  • 420-04-2

    单氰胺

  • +

  • 151-51-9

    聚碳化二亚胺

  • +

  • 109-77-3

    丙二腈

  • +

  • 75-50-3

    三甲胺

毒理性展开↓

生态数据:

根据国家和地方有关法规的要求处置。或与厂商或制造商联系,确定处置方法。

MSDS 展开↓

    Version 1.3
    Regulation (EC) No 1907/2006

    1 - Product and Company Information

    Product Name        POLYCARBODIIMIDE, 50 WT. % SOLUTION IN    
    PROPYLENE GLYCOL METHYL ETHER ACETATE

    2 - Hazards Identification

    SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
    May impair fertility. Flammable. Harmful by inhalation, in contact
    with skin and if swallowed. Irritating to eyes, respiratory system
    and skin.

    3 - Composition/Information on Ingredients

    Product Name        CAS #        EC no        Annex I    
    Index Number
    POLYCARBODIIMIDE, 50 WT. %        None        None        None    
    SOLUTION INPROPYLENE GLYCOL
    METHYL ETHER ACETATE
    Formula        CH2N2    

    4 - First Aid Measures

    AFTER INHALATION
    If inhaled, remove to fresh air. If not breathing give
    artificial respiration. If breathing is difficult, give oxygen.
    AFTER INGESTION
    If swallowed, wash out mouth with water provided person is
    conscious. Call a physician immediately.

    5 - Fire Fighting Measures

    EXTINGUISHING MEDIA
    Suitable: For small (incipient) fires, use media such as
    "alcohol" foam, dry chemical, or carbon dioxide. For large
    fires, apply water from as far as possible. Use very large
    quantities (flooding) of water applied as a mist or spray; solid
    streams of water may be ineffective. Cool all affected
    ALDRICH        www.molbase.com    
    containers with flooding quantities of water.
    SPECIAL RISKS
    Specific Hazard(s): Combustible liquid. Emits toxic fumes under
    fire conditions.
    SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
    Wear self-contained breathing apparatus and protective clothing
    to prevent contact with skin and eyes.

    6 - Accidental Release Measures

    PROCEDURE(S) OF PERSONAL PRECAUTION(S)
    Wear respirator, chemical safety goggles, rubber boots, and
    heavy rubber gloves.
    METHODS FOR CLEANING UP
    Absorb on sand or vermiculite and place in closed containers for
    disposal. Ventilate area and wash spill site after material
    pickup is complete.

    7 - Handling and Storage

    HANDLING
    Directions for Safe Handling: Do not breathe vapor. Avoid
    contact with eyes, skin, and clothing. Avoid prolonged or
    repeated exposure.
    STORAGE
    Conditions of Storage: Keep tightly closed. Keep away from heat
    and open flame. Store in a cool dry place.

    8 - Exposure Controls / Personal Protection

    ENGINEERING CONTROLS
    Mechanical exhaust required. Safety shower and eye bath.
    GENERAL HYGIENE MEASURES
    Wash contaminated clothing before reuse. Wash thoroughly after
    handling.
    PERSONAL PROTECTIVE EQUIPMENT
    Special Protective Measures: Wear appropriate government approved
    respirator, chemical-resistant gloves, safety goggles, other
    protective clothing.

    9 - Physical and Chemical Properties

    pH N/A
    BP/BP Range        154,000 °C    
    MP/MP Range        N/A    
    Flash Point        46,000 °C        Method: closed cup    
    Flammability        N/A    
    Autoignition Temp        N/A    
    Oxidizing Properties N/A
    Explosive Properties N/A
    Explosion Limits        N/A    
    Vapor Pressure        N/A    
    SG/Density        1,0300 g/cm3    
    Partition Coefficient N/A
    ALDRICH        www.molbase.com    
    Viscosity        N/A    
    Vapor Density        N/A    
    Saturated Vapor Conc. N/A
    Evaporation Rate        N/A    
    Bulk Density        N/A    
    Decomposition Temp.        N/A    
    Solvent Content        N/A    
    Water Content        N/A    
    Surface Tension        N/A    
    Conductivity        N/A    
    Miscellaneous Data        N/A    
    Solubility        N/A    

    10 - Stability and Reactivity

    STABILITY
    Stable: Stable.
    Conditions of Instability: Moisture.
    Conditions to Avoid: Moisture.
    Materials to Avoid: Strong acids.
    HAZARDOUS DECOMPOSITION PRODUCTS
    Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide,
    Nitrogen oxides.
    HAZARDOUS POLYMERIZATION
    Hazardous Polymerization: Will not occur

    11 - Toxicological Information

    SENSITIZATION
    Sensitization: Prolonged or repeated exposure may cause allergic
    reactions in certain sensitive individuals.
    SIGNS AND SYMPTOMS OF EXPOSURE
    Exposure can cause: Narcotic effect. Lung irritation, chest
    pain, and edema which may be fatal. CNS depression. Dermatitis.
    Gastrointestinal disturbances. Contact with eyes may cause
    blindness. To the best of our knowledge, the chemical, physical,
    and toxicological properties have not been thoroughly
    investigated.
    ROUTE OF EXPOSURE
    Skin Contact: Causes skin irritation.
    Skin Absorption: May be harmful if absorbed through the skin.
    Eye Contact: Causes eye irritation. Can cause blindness.
    Warning: exposure to vapor may cause eye injury, the onset of
    which may be delayed for several hours. Avoid all exposure to
    eyes.
    Inhalation: May be harmful if inhaled. Material is irritating to
    mucous membranes and upper respiratory tract.
    Ingestion: May be harmful if swallowed.
    TARGET ORGAN INFORMATION
    Nerves. Liver. Kidneys.
    CHRONIC EXPOSURE - REPRODUCTIVE HAZARD
    Result: Overexposure may cause reproductive disorder(s) based on
    tests with laboratory animals.

    ALDRICH        www.molbase.com    
    12 - Ecological Information

    No data available.

    13 - Disposal Considerations

    SUBSTANCE DISPOSAL
    This combustible material may be burned in a chemical incinerator
    equipped with an afterburner and scrubber. Observe all federal,
    state, and local environmental regulations.

    14 - Transport Information

    RID/ADR
    UN#: 1993
    Class: 3
    PG: III
    Proper Shipping Name: Flammable liquid, n.o.s.
    IMDG
    UN#: 1993
    Class: 3
    PG: III
    Proper Shipping Name: Flammable liquid, n.o.s.
    Marine Pollutant: No
    Severe Marine Pollutant: No
    Technical Name: Required
    IATA
    UN#: 1993
    Class: 3
    PG: III
    Proper Shipping Name: Flammable liquid, n.o.s.
    Inhalation Packing Group I: No
    Technical Name: Required

    15 - Regulatory Information

    CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
    INDICATION OF DANGER: T
    Toxic.
    R-PHRASES: 60-10-20/21/22-36/37/38
    May impair fertility. Flammable. Harmful by inhalation, in
    contact with skin and if swallowed. Irritating to eyes,
    respiratory system and skin.
    S-PHRASES: 53-16-26-36/37/39-45
    Avoid exposure - obtain special instructions before use. Keep
    away from sources of ignition - no smoking. In case of contact
    with eyes, rinse immediately with plenty of water and seek
    medical advice. Wear suitable protective clothing, gloves, and
    eye/face protection. In case of accident or if you feel unwell,
    seek medical advice immediately (show the label where possible).
    Caution: Substance not yet fully tested (EU).

    16 - Other Information

    WARRANTY
    The above information is believed to be correct but does not
    purport to be all inclusive and shall be used only as a guide. The
    ALDRICH        www.molbase.com    
    information in this document is based on the present state of our
    knowledge and is applicable to the product with regard to
    appropriate safety precautions. It does not represent any
    guarantee of the properties of the product. Inc.,
    shall not be held liable for any damage resulting from handling or
    from contact with the above product. See reverse side of invoice
    or packing slip for additional terms and conditions of sale.
    Copyright 2010 Co. License granted to make
    unlimitedpaper copies for internal use only.
    DISCLAIMER
    For R&D use only. Not for drug, household or other uses.
    ALDRICH        www.molbase.com    


SECTION 16 - ADDITIONAL INFORMATION
N/A

分子结构与计算化学数据展开↓

计算化学数据


1.疏水参数计算参考值(XlogP):1.1

2.氢键供体数量:2

3.氢键受体数量:2

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积47.7

7.重原子数量:3

8.表面电荷:0

9.复杂度:18.3

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

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