二甲基氧化膦

二甲基氧化膦 基本信息
CAS号 7211-39-4 分子式 C2H7OP
分子量 78.05010 精确质量  78.02350
PSA  40.54000 LogP  0.80570

基本信息 展开↓

CAS号:
7211-39-4
3D弹球模型:
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分子式:
C2H7OP
分子量:
78.05010
中文名称:
二甲基氧化膦
英文名称:
dimethyl(oxo)phosphanium
中文别名:
二甲基氧化膦;
ethyl 2,4-dimethyl-1,3-thiazole-5-carboxylate;
Ethyl 2,4-dimethylthiazole-5-carboxylate;
Ethyl 4-methyl-1,3-thiazole-2-carboxylate;
2-Thiazolecarboxylic acid, 4-methyl-, ethyl ester;
2-Thiazolecarboxylicacid, 4-methyl-, ethyl ester;
p-Chlorfenyl-chlormethylsulfid;
p-Chlorfenyl-chlormethylsulfid [Czech];
p-Chlorfenylmerkaptomethylchlorid;
p-Chlorfenylmerkaptomethylchlorid [Czech];
p-Chloro-S-chloromethylbenzenethiol;
Chloromethyl 4-chlorophenyl sulphide;
1-chloro-4-[(chloromethyl)sulfanyl]benzene;
Chloromethyl 4-chlorophenyl sulfide;
2-methyl-N-methylidynepropan-2-aminium;
TERT-BUTYL ISOCYANIDE;
Didecyldimonium chloride;
Didecildimethylammonium chloride;
N-decyl-N,N-dimethyldecan-1-aminium chloride;
N,N-Dimethyl-N,N-dioctadecylammonium chloride;
Didecyl Dimethylammonium chloride;
didecyldimethylammonium chloride;
Lake Fast Violet RL;
Lake Fast Violet RLB;
Lionogen Violet R 6100;
Lionogen Violet RL;
Lionol Violet HR;
Monolite Fast Violet R;
PV Fast Violet BL;
PV Fast Violet RL-SPE;
Paliogen Violet 5890;
Paliogen Violet L 5890;
Permane
英文别名:
dimethyl(oxo)phosphanium;
dimethyl-oxo-phosphanium;
EINECS 230-591-2;
Phosphine oxide,dimethyl;
Dimethylphosphanoxid
精确分子量/精确质量:
78.02350
极性分子表面积/PSA:
40.54000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
EINECS:
230-591-2
InChI:
InChI=1/C2H7OP/c1-4(2)3/h4H,1-2H3

物化性质展开↓

沸点:
84.5ºC at 760 mmHg
闪点:
4.906ºC

合成路线查看所有的合成路线

  • 676-58-4

    甲基氯化镁

  • +

  • 762-04-9

    亚磷酸二乙酯

  • ~80%

  • 7211-39-4

    二甲基氧化膦

  • 74-87-3

    氯甲烷

  • ~5%

  • 16394-14-2

    16394-14-2

  • +

  • 2914-38-7

    2914-38-7

  • +

  • 7211-39-4

    二甲基氧化膦

  • +

  • 87930-22-1

    methylphosphonous acid sodium salt

  • 3283-12-3

    二甲基磷酸

  • +

  • 603-35-0

    三苯基膦

  • 7211-39-4

    二甲基氧化膦

  • +

  • 791-28-6

    三苯基氧化膦

MSDS 展开↓


Section 1: Product Identification
   Chemical Name:       Dimethylphosphine oxide, min. 97%    
   CAS Registry Number:       7211-39-4    
   Formula:       (CH3)2P(O)H    
   EINECS Number:       none    
   Chemical Family:       organophosphorus compound    
   Synonym:       Dimethylphosphorus oxide    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title compound       7211-39-4       100%       no data       no data    

Section 3: Hazards Identification
   Emergency Overview:       Irritating to skin, eyes and respiratory tract. May be harmful if swallowed.    
   Primary Routes of Exposure:       Inhalation, skin, eyes.    
   Eye Contact:       Causes moderate irritation of the eyes.    
   Skin Contact:       Causes irritation of the skin. May cause redness, itching and pain.    
   Inhalation:       Irritating to the nose, mucous membranes and respiratory tract.    
   Ingestion:       No specific information is available on the physiological effects of ingestion. May be harmful if swallowed.    
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.    
   Chronic Health Affects:       No information on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       no data    
   Autoignition Temperature:       no data    
   Explosion Limits:       no data    
   Extinguishing Medium:       carbon dioxide, dry powder or foam.    
   Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus
   Special Fire Fighting Procedures:
   and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic organic fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: Contact of dimethylphosphine oxide with carbon tetrachloride leads to explosive decomposition.

SECTION 6: Accidental Release Measures
   Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and
   Spill and Leak Procedures:
   swept up.

SECTION 7: Handling and Storage
   Handling and Storage:       Keep container tightly closed. Store in a cool, dry place.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       Handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       white solid    
   Molecular Weight:       78.05    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       musty odor    
   Solubility in Water:       slightly soluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       contact with carbon tetrachloride leads to explosive decomposition.    
   Incompatibility:       oxidizing agents, active metals, carbon tetrachloride and halogens.    
   Decomposition Products:       carbon dioxide, carbon monoxide, organic fumes and phosphorus oxides.    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       no data    
   Mutagenic Effects:       no data    
   Tetratogenic Effects:       no data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to federal, state, and local regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

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