2,4-二硝基苯酯

2,4-二硝基苯酯 基本信息
CAS号 4232-27-3 分子式 C8H6N2O6
分子量 226.14300 精确质量  226.02300
PSA  117.94000 LogP  2.47470

基本信息 展开↓

CAS号:
4232-27-3
3D弹球模型:
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分子式:
C8H6N2O6
分子量:
226.14300
中文名称:
2,4-二硝基苯酯
英文名称:
(2,4-dinitrophenyl) acetate
中文别名:
2,4-二硝基苯酯;
2,4-二硝基乙酸苯酯
英文别名:
(2,4-dinitrophenyl) acetate;
2,4-DINITROPHENYL ACETATE;
2,4-Dinitrophenyl acetate;
ghl.PD_Mitscher_leg0.305;
2,4-(NO2)2C6H3OAc;
acetic acid-(2,4-dinitro-phenyl ester);
1-acetoxy-2,4-dinitro-benzene;
2.4-Dinitro-1-acetoxy-benzol;
CDMLJWCAUSWULM-UHFFFAOYSA;
Essigsaeure-(2,4-dinitro-phenylester);
Phenol,2,4-dinitro-,acetate (ester)
精确分子量/精确质量:
226.02300
极性分子表面积/PSA:
117.94000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
EINECS:
224-189-6
InChI:
The Key: CDMLJWCAUSWULM-UHFFFAOYSA-N

物化性质展开↓

密度:
1.5g/cm3
熔点:
69ºC
沸点:
366.4ºC at 760 mmHg
闪点:
180.2ºC
折射率:
1.587

安全信息展开↓

海关代码:
2915390090

合成路线查看所有的合成路线

  • 51-28-5

    2,4-二硝基酚

  • +

  • 104293-02-9

    acetic acid,1-ethoxy-2-trimethylsilylethenol

  • ~99%

  • 4232-27-3

    2,4-二硝基苯酯

  • 51-28-5

    2,4-二硝基酚

  • +

  • 75-36-5

    乙酰氯

  • ~89%

  • 4232-27-3

    2,4-二硝基苯酯

  • 51-28-5

    2,4-二硝基酚

  • +

  • 108-24-7

    乙酸酐

  • ~85%

  • 4232-27-3

    2,4-二硝基苯酯

MSDS 展开↓

Name: 2 4-Dinitrophenyl Acetate Material Safety Data Sheet
Synonym: None
CAS: 4232-27-3
Section 1 - Chemical Product   MSDS Name:2 4-Dinitrophenyl Acetate Material Safety Data Sheet
Synonym:None

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
4232-27-3 Phenol, 2,4-dinitro-, acetate (ester) 100 224-189-6
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation. The toxicological properties of this material have not been fully investigated.
Skin:
May cause skin irritation. The toxicological properties of this material have not been fully investigated.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 4232-27-3: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 71.00 - 73.00 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C8H6N2O6
Molecular Weight: 226.15

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 4232-27-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Phenol, 2,4-dinitro-, acetate (ester) - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 4232-27-3: No information available.
Canada
CAS# 4232-27-3 is listed on Canada's NDSL List.
CAS# 4232-27-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 4232-27-3 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

海关数据查看详细

中国海关编码:2915390090

概述:
2915390090. 其他乙酸酯. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:5.5%. 普通关税:30.0%
申报要素:
品名, 成分含量, 用途
监管条件:
A.入境货物通关单B.出境货物通关单
检验检疫:
R.进口食品卫生监督检验S.出口食品卫生监督检验M.进口商品检验N.出口商品检验
摘要/Summary:
2915390090. esters of acetic acid. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:5.5%. General tariff:30.0%

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