二乙烯基二氯化锡

二乙烯基二氯化锡 基本信息
CAS号 7532-85-6 分子式 C4H6Cl2Sn
分子量 243.69700 精确质量  243.88700
PSA  0.00000 LogP  2.35660

基本信息 展开↓

CAS号:
7532-85-6
3D弹球模型:
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分子式:
C4H6Cl2Sn
分子量:
243.69700
中文名称:
二乙烯基二氯化锡
英文名称:
dichloro-bis(ethenyl)stannane
中文别名:
二乙烯基二氯化锡
英文别名:
dichloro-bis(ethenyl)stannane;
Dichlor-di-vinyl-stannan;
Di-ethenylzinndichlorid;
Stannane,dichlorodiethenyl;
Dichlorodivinylstannane;
divinyltin(IV) dichloride;
EINECS 231-399-1;
DIVINYLTIN DICHLORIDE;
Sn(vinyl)2Cl2
精确分子量/精确质量:
243.88700
极性分子表面积/PSA:
0.00000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
贝尔斯坦号/MDL:
MFCD00058728
EINECS:
231-399-1
InChI:
The Key: LWHKXKZPLXYXRO-UHFFFAOYSA-L

物化性质展开↓

沸点:
54ºC (3 torr)
闪点:
54-56°C/3mm
存储条件/存储方法:

密封于阴凉干燥环境。

稳定性相关:

如果遵照规格使用和储存则不会分解。

其它信息:

1.       性状:无可用

2.       密度(g/mL,25/4): 无可用

3.       相对蒸汽密度(g/mL,空气=1):无可用

4.       熔点(ºC):无可用

5.       沸点(ºC,常压):54-56

6.       沸点(ºC,5.2kPa): 无可用

7.       折射率: 无可用

8.       闪点(ºC): 54-56

9.       比旋光度(º):无可用

10.    自燃点或引燃温度(ºC):无可用

11.    蒸气压(kPa,25ºC):无可用

12.    饱和蒸气压(kPa,60ºC):无可用

13.    燃烧热(KJ/mol):无可用

14.    临界温度(ºC):无可用

15.    临界压力(KPa):无可用

16.    油水(辛醇/水)分配系数的对数值:无可用

17.    爆炸上限(%,V/V):无可用

18.    爆炸下限(%,V/V): 无可用

19.    溶解性:无可用

安全信息展开↓

包装等级:
II
风险类别:
6.1

合成路线查看所有的合成路线

  • 10008-90-9

    chloro-tris(ethenyl)stannane

  • 1112-56-7

    四乙烯基锡

  • +

  • 7532-85-6

    二乙烯基二氯化锡

  • 1112-56-7

    四乙烯基锡

  • +

  • 13453-32-2

    氯化铊(Ⅲ)

  • 7532-85-6

    二乙烯基二氯化锡

  • 1112-56-7

    四乙烯基锡

  • +

  • 7646-78-8

    无水四氯化锡

  • 10008-90-9

    chloro-tris(ethenyl)stannane

  • +

  • 7532-85-6

    二乙烯基二氯化锡

毒理性展开↓

毒理学数据:

1
试验方法:口服
摄入剂量: 500毫克/千克
测试对象:啮齿动物-
毒性类型:急性
毒性作用:详细的毒副作用没有报告以外的其他致死剂量值。
2

试验方法:吸入
摄入剂量: “ 933 mg/m3/1H
测试对象:啮齿动物-
毒性类型:急性
毒性作用: 1.流泪
2.
嗜睡(普通抑郁活动)
3.
,胸部或呼吸-呼吸困难

3

试验方法:行政到眼睛
摄入剂量: 100 uL/24H
测试对象:啮齿动物-
毒性类型: SkinEyeIrrition
毒性作用:详细的毒副作用没有报告以外的其他致死剂量值。

生态数据:

该物质对环境可能有危害,对水体应给予特别注意。

MSDS 展开↓


Section 1: Product Identification
   Chemical Name:       Divinyltin dichloride, 98%    
   CAS Registry Number:       7532-85-6    
   Formula:       (CH2=CH)2SnCl2    
   EINECS Number:       231-399-1    
   Chemical Family:       organotin compound    
   Synonym:       Dichlorodiethenylstannane    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       7532-85-6       100%       0.1mg/m3       0.1mg/m3    

Section 3: Hazards Identification
   Emergency Overview:       Corrosive to skin, eyes and respiratory tract. Harmful if swallowed,    
   Primary Routes of Exposure:       Ingestion, inhalation, skin, eyes    
   Eye Contact:       Causes severe burns to the eyes and blindness.    
   Skin Contact:       Prolonged contact will cause redness and corrosive acid burns to the skin.    
   Corrosive to the nose, mucous membranes and respiratory tract. High doses may cause long term
   Inhalation:
   neurological damage.
   Harmful if swallowed. Delayed and permanent psycho-neurologic disturbances; impairment of vision,
   Ingestion:
   unsteadiness, nausea and vomiting.
   Corrosive to skin, eyes and mucous membranes. Ingestion of certain organotin compounds may cause
   Acute Health Affects:
   delayed poisoning (4 days) with cerebral edema causing damage to the central nervous system.
   Repeated exposure to certain organic tin compounds may cause problems with vision, skin, respiratory
   Chronic Health Affects:
   system, central nervous system, liver, kidneys, urinary tract, and blood.
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       no data    
   Autoignition Temperature:       no data    
   Explosion Limits:       no data    
   Extinguishing Medium:       carbon dioxide, foam or dry powder    
   Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus
   Special Fire Fighting Procedures:
   and full protective clothing.
   Hazardous Combustion and       carbon monoxide, carbon dioxide, soot, organic fumes and tin compounds.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Small spills can be neutralized with powdered sodium bicarbonate, lime, or calcium carbonate and swept up.
   Spill and Leak Procedures:       Large spills in areas not adequately ventilated will require an evacuation of site. Emergency response teams    
   will require self-contained breathing apparatus.

SECTION 7: Handling and Storage
   Handling and Storage:       Store in a cool, dry, well ventilated area away from heat and direct sunlight. Keep containers tightly sealed.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.    
   Ventilation:       Work with this product in a well-ventilated area, preferably a fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Work with this product in a well-ventilated area, preferably a fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       colorless liq.    
   Molecular Weight:       243.69    
   Melting Point:       no data    
   Boiling Point:       54-56°C /3 mm    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       irritating odor    
   Solubility in Water:       insoluble    

SECTION 10: Stability and Reactivity
   Stability:       moisture sensitive    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       strong oxidizing agents and halogens    
   Decomposition Products:       carbon monoxide, carbon dioxide, tin oxide, and organic fumes.    

SECTION 11: Toxicological Information
   Administration into the eye (rabbit); Standard Draize Test: 100ul/24H. Oral (rat); LDLo: 500mg/kg. Inhalation
   RTECS Data:
   (rat); LC: >933mg/m3/1H.
   Carcinogenic Effects:       No data available    
   Mutagenic Effects:       No data available    
   Tetratogenic Effects:       No data available    

SECTION 12: Ecological Information
   Avoid release to groundwater or waterways. Very toxic to aquatic organisms. May cause long-term adverse
   Ecological Information:
   effects.

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to federal, state, and local regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Corrosive liquids, N.O.S.    
   Hazard Class (CFR):       8    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       II    
   UN ID Number (CFR):       UN# 1760    
   Shipping Name (IATA):       Corrosive liquid, N.O.S.    
   Hazard Class (IATA):       8    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       II    
   UN ID Number (IATA):       UN# 1760    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

分子结构与计算化学数据展开↓

分子结构数据


1摩尔折射率:无可用

2、   摩尔体积(cm3/mol): 无可用

3、   等张比容(90.2K):无可用

4、   表面张力(dyne/cm):无可用

5、   极化率:无可用

计算化学数据


1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:0

4.可旋转化学键数量:2

5.互变异构体数量:无

6.拓扑分子极性表面积0

7.重原子数量:7

8.表面电荷:0

9.复杂度:77.7

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

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