(4R,5R)-4,5-二乙氧基羰基-2,2-二甲基二氧

(4R,5R)-4,5-二乙氧基羰基-2,2-二甲基二氧 基本信息
CAS号 59779-75-8 分子式 C11H18O6
分子量 246.25700 精确质量  246.11000
PSA  71.06000 LogP  0.63270

基本信息 展开↓

CAS号:
59779-75-8
3D弹球模型:
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分子式:
C11H18O6
分子量:
246.25700
中文名称:
(4R,5R)-4,5-二乙氧基羰基-2,2-二甲基二氧
英文名称:
(-)-Diethyl 2,3-O-isopropylidene-L-tartrate
中文别名:
(4R,5R)-4,5-二乙氧基羰基-2,2-二甲基二氧;
(4R,5r)-4,5-二乙氧基羰基-2,2-二甲基二氧杂烷;
(-)-2,3-O-异丙亚基-L-酒石酸二乙酯
英文别名:
(-)-Diethyl 2,3-O-isopropylidene-L-tartrate;
(4R,5R)-4,5-DIETHOXYCARBONYL-2,2-DIMETHYL DIOXOLANE
精确分子量/精确质量:
246.11000
极性分子表面积/PSA:
71.06000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
贝尔斯坦号/MDL:
MFCD00143372
InChI:
The Key: MCNKHXZIPATURB-HTQZYQBOSA-N

物化性质展开↓

密度:
1.132g/cm3
沸点:
92-93ºC
闪点:
120.2ºC
折射率:
1.4345-1.4365

安全信息展开↓

安全说明:
S24/25
安全标志:
S24/25:防止皮肤和眼睛接触。

合成路线查看所有的合成路线

  • 87-91-2

    L-(+)-酒石酸二乙酯

  • +

  • 116-11-0

    2-甲氧基丙烯

  • ~97%

  • 59779-75-8

    (4R,5R)-4,5-二乙氧基羰基-2,2-二甲基二氧

  • 87-91-2

    L-(+)-酒石酸二乙酯

  • +

  • 67-64-1

    丙酮

  • ~96%

  • 59779-75-8

    (4R,5R)-4,5-二乙氧基羰基-2,2-二甲基二氧

  • 87-91-2

    L-(+)-酒石酸二乙酯

  • +

  • 77-76-9

    2,2-二甲氧基丙烷

  • ~96%

  • 59779-75-8

    (4R,5R)-4,5-二乙氧基羰基-2,2-二甲基二氧

MSDS 展开↓

Name: (4R 5R)-4 5-Diethoxycarbonyl-2 2-Dimethyl Dioxolane 97% Material Safety Data Sheet
Synonym: (4R-Trans)-2,2-Dimethyl-1,3-Dioxolane-4,5-Dicarboxylic Acid Diethyl Ester; Diethyl (4R-Trans)-2,2-Dimethyl -1,3-Dioxolane-4,5-Dicarboxylate
CAS: 59779-75-8
Section 1 - Chemical Product   MSDS Name:(4R 5R)-4 5-Diethoxycarbonyl-2 2-Dimethyl Dioxolane 97% Material Safety Data Sheet
Synonym:(4R-Trans)-2,2-Dimethyl-1,3-Dioxolane-4,5-Dicarboxylic Acid Diethyl Ester; Diethyl (4R-Trans)-2,2-Dimethyl -1,3-Dioxolane-4,5-Dicarboxylate

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
59779-75-8 (4R,5R)-4,5-Diethoxycarbonyl-2,2-Dimet 97% unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place. Keep container closed when not in use.
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 59779-75-8: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: clear yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: soluble in chloroform,methanol,ethanol,a
Specific Gravity/Density:
Molecular Formula: C11H18O6
Molecular Weight: 246.26

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 59779-75-8 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
(4R,5R)-4,5-Diethoxycarbonyl-2,2-Dimethyl Dioxolane - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 59779-75-8: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 59779-75-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 59779-75-8 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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