高氯酸钠 一水合物

高氯酸钠 一水合物 基本信息
CAS号 7791-07-3 分子式 ClH2NaO5
分子量 140.45600 精确质量  139.94900
PSA  83.50000 LogP  0.15000

基本信息 展开↓

CAS号:
7791-07-3
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分子式:
ClH2NaO5
分子量:
140.45600
中文名称:
高氯酸钠 一水合物
英文名称:
Sodium perchlorate monohydrate
中文别名:
高氯酸钠 一水合物;
高氯酸钠,一水合物;
一水高氯酸钠;
高氯酸钠,一水
英文别名:
Sodium perchlorate monohydrate;
sodium,perchlorate,hydrate
精确分子量/精确质量:
139.94900
极性分子表面积/PSA:
83.50000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
贝尔斯坦号/MDL:
MFCD00149164
EINECS:
231-511-9
PubChem:
24889182
InChI:
InChI=1/ClHO4.Na.H2O/c2-1(3,4)5;;/h(H,2,3,4,5);;1H2/q;+1;/p-1

生产制备方法及用途展开↓

制备方法


1.用Na2CO3处理HClO4水溶液。从NaClO4水溶液中析出结晶。在空气中无水NaClO4逐渐吸湿生成一水合物。 2.先将饱和的氯酸钠溶液用氢氧化钡除去铬酸根等杂质,过滤后作为电解液进行电解: 控制电流强度为1500A,槽电压5~6V,PH=6~7,电解液温度为50~70℃。当92%~96%的氯酸钠转化时,停止电解。将所得电解液过滤,滤液蒸发至浆状,所得结晶甩干后逐渐升温至220~230℃进行干燥,即为成品。

合成制备方法


1.用Na2CO3处理HClO4水溶液。从NaClO4水溶液中析出结晶。在空气中无水NaClO4逐渐吸湿生成一水合物。

2.先将饱和的氯酸钠溶液用氢氧化钡除去铬酸根等杂质,过滤后作为电解液进行电解:

控制电流强度为1500A,槽电压5~6V,PH=6~7,电解液温度为50~70℃。当92%~96%的氯酸钠转化时,停止电解。将所得电解液过滤,滤液蒸发至浆状,所得结晶甩干后逐渐升温至220~230℃进行干燥,即为成品。

用途简介


1.用于制造高氯酸或其他高氯酸盐,还用于火药工业

用途


1.用于制造高氯酸或其他高氯酸盐,还用于火药工业。

2.分析试剂。氧化剂。有腐蚀性。

物化性质展开↓

外观与性状:
白色粘附性的晶体
密度:
2,02 g/cm3
熔点:
130 °C
存储条件/存储方法:

放入紧密的贮藏器内,储存在阴凉,干燥的地方。

稳定性相关:

避免接触还原剂,有机材料,金属粉末,水分/潮湿。易溶于水,15℃,100cm3水可溶209g,50℃,100cm3水可溶284g。可溶于乙醇,密度2.02g/cm3。在浓硫酸干燥或加热到50℃失去结晶水。

其它信息:

1.      性状:无色斜方晶体。吸湿。

2.      密度(g/mL 25ºC):2.02

3.      相对蒸汽密度(g/mL,空气=1):未确定

4.      熔点(ºC):130

5.      沸点(ºC,常压):未确定

6.      沸点(ºC,5.2kPa):未确定

7.      折射率(n20/D):未确定

8.      闪点(ºC,):未确定

9.      比旋光度(º):未确定

10.   自燃点或引燃温度(ºC):未确定

11.   蒸气压(kPa,25ºC):未确定

12.   饱和蒸气压(kPa,60ºC):未确定

13.   燃烧热(KJ/mol):未确定

14.   临界温度(ºC):未确定

15.   临界压力(KPa):未确定

16.   油水(辛醇/水)分配系数的对数值(25℃):未确定

17.   爆炸上限(%,V/V):未确定

18.   爆炸下限(%,V/V):未确定

19.   溶解性(mg/mL) :易溶于水,溶于乙醇和丙酮,不溶于乙醚。

安全信息展开↓

包装等级:
II
风险类别:
5.1
海关代码:
2829199000
WGK_Germany:
3
德国有关水污染物质的分类清单
危险类别码:
R9
安全说明:
S17-S26-S27-S36/37/39-S22-S13
RTECS号:
SC9850000
安全标志:
S13:远离食品、饮料和动物饲料。
S22:不要吸入粉尘。
S27:立刻除去所有污染衣物。
:
危险标志:
O,Xn,Xi

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    高氯酸钠 一水合物

毒理性展开↓

CHEMICAL IDENTIFICATION

RTECS NUMBER :
SC9850000
CHEMICAL NAME :
Perchloric acid, sodium salt, monohydrate
CAS REGISTRY NUMBER :
7791-07-3
LAST UPDATED :
199307
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
Cl-O4.Na.H2-O
MOLECULAR WEIGHT :
140.46

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1150 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JAFCAU Journal of Agricultural and Food Chemistry. (American Chemical Soc., Distribution Office Dept. 223, POB 57136, West End Stn., Washington, DC 20037) V.1- 1953- Volume(issue)/page/year: 14,512,1966
毒理学数据:

低毒,半数致死量(大鼠,经口)LD50:2100mg/kg;

生态数据:

对水是稍微危害的,若无政府许可,勿将材料排入周围环境。

MSDS 展开↓

Name: Sodium Perchlorate Monohydrate P.A. Material Safety Data Sheet
Synonym: None known
CAS: 7791-07-3
Section 1 - Chemical Product   MSDS Name:Sodium Perchlorate Monohydrate P.A. Material Safety Data Sheet
Synonym:None known

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
7791-07-3 Sodium Perchlorate Monohydrate ca 100 unlisted
Hazard Symbols: XN O
Risk Phrases: 22 9

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Harmful if swallowed. Explosive when mixed with combustible material.
Potential Health Effects
Eye:
Causes eye irritation. May cause conjunctivitis. May cause permanent corneal opacification.
Skin:
May cause severe irritation and possible burns.
Ingestion:
May cause burns to the gastrointestinal tract. May cause nausea, vomiting, and diarrhea, possibly with blood.
Inhalation:
Causes respiratory tract irritation. May cause acute pulmonary edema, asphyxia, chemical pneumonitis, and upper airway obstruction caused by edema.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Effects may be delayed.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid if cough or other symptoms appear. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with combustible materials may cause a fire. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water with caution and in flooding amounts. Some oxidizers may react explosively with hydrocarbons(fuel). May accelerate burning if involved in a fire. Containers may explode when heated.
Extinguishing Media:
Use water only! Contact professional fire-fighters immediately. For small fires, do NOT use dry chemicals, carbon dioxide, halon or foams. USE WATER ONLY. For large fires flood fire with water from a distance.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Do not use combustible materials such as paper towels to clean up spill.

Section 7 - HANDLING and STORAGE
  Handling:
Use with adequate ventilation. Minimize dust generation and accumulation. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed.
Avoid contact with clothing and other combustible materials. Do not get on skin or in eyes. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Do not store near combustible materials. Store in a cool, dry place. Keep away from reducing agents.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear a chemical apron. Wear appropriate clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Appearance: colorless or white
Odor: odorless
pH: 6-8 (5% solution)
Vapor Pressure: Not applicable.
Viscosity: Not applicable.
Boiling Point: 482 deg F
Freezing/Melting Point: 266 deg F
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 482 deg F
Solubility in water: 209% @ 15 C
Specific Gravity/Density: 2.02
Molecular Formula: NaO4Cl.H20
Molecular Weight: 140

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, combustible materials, reducing agents.
Incompatibilities with Other Materials:
Reducing agents.
Hazardous Decomposition Products:
Chlorine, oxygen.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 7791-07-3: SC9850000 LD50/LC50:
Not available.
Carcinogenicity:
Sodium Perchlorate Monohydrate - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN O
Risk Phrases:
R 22 Harmful if swallowed.
R 9 Explosive when mixed with combustible material.
Safety Phrases:
S 13 Keep away from food, drink and animal feeding
stuffs.
S 22 Do not breathe dust.
S 27 Take off immediately all contaminated clothing.
WGK (Water Danger/Protection)
CAS# 7791-07-3: No information available.
United Kingdom Occupational Exposure Limits
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 7791-07-3 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
US FEDERAL
TSCA
CAS# 7791-07-3 is not on the TSCA Inventory. It is a hydrate and
exempt from TSCA Inventory requirements (40CFR720.3(u)(2)).


SECTION 16 - ADDITIONAL INFORMATION
N/A

分子结构与计算化学数据展开↓

分子结构数据


1、摩尔折射率:无可用的

2、摩尔体积(cm3/mol):无可用的

3、等张比容(90.2K):无可用的

4、表面张力(dyne/cm):无可用的

5、介电常数:无可用的

6、极化率(10-24cm3):无可用的

7、单一同位素质量:139.948846 Da

8、标称质量:140 Da

9、平均质量:140.4556 Da

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