正硅酸四乙酯

正硅酸四乙酯 基本信息
CAS号 562-90-3 分子式 C8H12O8Si
分子量 264.26200 精确质量  264.03000
PSA  105.20000 LogP  -0.32560

基本信息 展开↓

CAS号:
562-90-3
3D弹球模型:
立即前往扯扯看
分子式:
C8H12O8Si
分子量:
264.26200
中文名称:
正硅酸四乙酯
英文名称:
Silicon(IV) Acetate
中文别名:
正硅酸四乙酯;
乙酸硅(IV)
英文别名:
Silicon(IV) Acetate;
SILICON TETRAACETATE
精确分子量/精确质量:
264.03000
极性分子表面积/PSA:
105.20000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
贝尔斯坦号/MDL:
MFCD00026184
EINECS:
209-239-7
PubChem:
24888344
BRN:
994868
InChI:
InChI=1/4C2H4O2.Si/c4*1-2(3)4;/h4*1H3,(H,3,4);/q;;;;+4/p-4

生产制备方法及用途展开↓

合成制备方法


图XIv-5 四醋酸硅的合成装置

1-带平衡和无水氯化钙干燥管的滴液漏斗;2-吸液玻璃管;3-活塞;4-抽滤瓶(按真空系统)

用四氯化硅与醋酸酐反应即得四醋酸硅。

图四醋酸硅的合成装置

1—带平衡管和无水氯化钙干燥管的滴液漏斗;

2—吸液玻璃管;3—活塞;

4—抽滤瓶(按真空系统)

反应装置如图所示,将255g(1.5mol)四氯化硅放入1L的三颈圆底烧瓶中,在电磁搅拌下,由滴液漏斗滴入704g(69mol过量15%)乙酸酐。反应装置应以无水氯化钙干燥管隔绝潮气,在反应过程中吸液玻璃管应在较高位置。

以不触及反应液为好,应关闭活塞3。

四氯化硅和醋酸酐的反应为放热反应,反应后反应混合物带色,并开始析出四醋酸硅的晶体,完成反应后将反应物放置数日,再用干冰丙酮浴冷却后,打开活塞3,通过管2将上层清液(含乙酰氯和醋酸酐)吸入抽滤瓶4。四醋酸硅粗品用100mL醋酸酐重结晶,用回流装置,在电热套上加热至100℃,再冰浴冷至0℃使其结晶完全,滤集晶体再如法重结晶,醋酸酐用75mL,精制的四醋酸硅在室温下晾干或真空干燥,再在100℃下干燥数小时,即得产品约335g,产率84.5%。

用途


 

 

物化性质展开↓

外观与性状:
白色至米色晶体或结晶粉末
密度:
1,18 g/cm3
熔点:
111-115 °C(lit.)
沸点:
148 °C5 mm Hg(lit.)
闪点:
>110°C
蒸汽密度:
>1 (vs air)
存储条件/存储方法:

贮存:

将密器密封,储存密封的主藏器内,并放在阴凉, 干爽的位置。

稳定性相关:

稳定性和反应性:

要避免的物料:水分,潮湿。

要分解的产品:一氧化碳和二氧化碳,乙酰酸。

其它信息:

一、物性数据

1.       性状:无色结晶。

2.       密度(g/mL,25/4℃):1.18

3.       相对蒸汽密度(g/mL,空气=1):不确定

4.       熔点(ºC):110

5.       沸点(ºC,0.67kpa或5 mmHg):148

6.       折射率:不确定

7.       闪点(ºC):不确定

8.       比旋光度(ºC):不确定

9.       自燃点或引燃温度(ºC)不确定

10.    蒸气压(kPa,25ºC):不确定

11.    饱和蒸气压(kPa,60ºC):不确定

12.    燃烧热(KJ/mol):不确定

13.    临界温度(ºC):不确定

14.    临界压力(KPa):不确定

15.    油水(辛醇/水)分配系数的对数值:不确定

16.    爆炸上限(%,V/V):不确定

17.    爆炸下限(%,V/V):不确定

18.    溶解性:可溶于丙酮、苯等溶剂。

安全信息展开↓

包装等级:
II
风险类别:
8
海关代码:
2915900090
WGK_Germany:
3
德国有关水污染物质的分类清单
危险类别码:
R34
安全说明:
S26-S36/37/39-S45
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
S45:出现意外或者感到不适,立刻到医生那里寻求帮助(最好带去产品容器标签)。
:
危险标志:
C:Corrosive;

合成路线查看所有的合成路线

  • 108-24-7

    乙酸酐

  • ~96%

  • 562-90-3

    正硅酸四乙酯

  • 10026-04-7

    四氯硅烷

  • ~83%

  • 562-90-3

    正硅酸四乙酯

  • 141-78-6

    乙酸乙酯

  • 562-90-3

    正硅酸四乙酯

毒理性展开↓

生态数据:

三、生态学数据:

1、其它有害作用:该物质对环境可能有危害,对水体应给予特别注意。

MSDS 展开↓


Section 1: Product Identification
   Chemical Name:       Silicon (IV) acetate, min. 95%    
   CAS Registry Number:       562-90-3    
   Formula:       Si(OOCCH3)4    
   EINECS Number:       209-239-7    
   Chemical Family:       metal acetate salt    
   Synonym:       Silicon tetraacetate    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       562-90-3       100%       no data       no data    

Section 3: Hazards Identification
   Corrosive to skin, eyes, and mucous membranes. May cause coughing, wheezing, shortness of breath,
   Emergency Overview:
   headache, nausea and vomiting. Ingestion may cause damage to the mouth, throat and esophagus.
   Primary Routes of Exposure:       Ingestion, inhalation, skin, eyes.    
   Eye Contact:       Corrosive to eyes.    
   Skin Contact:       Corrosive to skin.    
   Inhalation:       Inhalation may cause inflammation of the respiratory tract, edema and chemical pneumonitis.    
   Ingestion:       Ingestion may cause damage to the mouth, throat and esophagus.    
   Corrosive to skin, eyes and mucous membranes. Inhalation causes coughing, wheezing, shortness of breath,
   Acute Health Affects:
   headache, nausea, and vomiting. Ingestion may cause damage to the mouth throat and esophagus.
   Chronic Health Affects:       Prolonged inhalation of inorganic silicon compounds may cause pulmonary fibrosis know as silicosis.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       no data    
   Explosion Limits:       no data    
   Extinguishing Medium:       carbon dioxide or dry powder    
   Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus
   Special Fire Fighting Procedures:
   and full protective clothing.
   Hazardous Combustion and       If involved in a fire, this material may emit toxic and corrosive fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Sweep up the solid and dispose of properly.    

SECTION 7: Handling and Storage
   Handling and Storage:       Store the material in a sealed container. Store cold. Keep away from heat.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.    
   Ventilation:       To minimize exposure, handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       To minimize exposure, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       white xtl.    
   Molecular Weight:       264.27    
   Melting Point:       160° dec.    
   Boiling Point:       148°C /6mm(110°subl.)    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       not determined    
   Solubility in Water:       reacts with water    

SECTION 10: Stability and Reactivity
   Stability:       moisture sensitive (store cold)    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       contact with moisture    
   Incompatibility:       oxidizing agents, water, strong bases, and halogens    
   Decomposition Products:       carbon monoxide, carbon dioxide, silicon dioxide and organic fumes.    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       No data available    
   Mutagenic Effects:       No data available    
   Tetratogenic Effects:       No data available    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to federal, state, and local regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Corrosive Solids, N.O.S.    
   Hazard Class (CFR):       8    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       III    
   UN ID Number (CFR):       UN# 1759    
   Shipping Name (IATA):       Corrosive Solid, N.O.S.    
   Hazard Class (IATA):       8    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       III    
   UN ID Number (IATA):       UN# 1759    

SECTION 15: Regulatory Information
   TSCA:       Listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

海关数据查看详细

中国海关编码:2915900090

概述:
2915900090. 其他饱和无环一元羧酸及其酸酐(酰卤、过氧)化物、过氧酸及其卤化、硝化、磺化、亚硝化衍生物. 增值税率:17.0%. 退税率:9.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:5.5%. 普通关税:30.0%
申报要素:
品名, 成分含量, 用途
监管条件:
A.入境货物通关单B.出境货物通关单
检验检疫:
R.进口食品卫生监督检验S.出口食品卫生监督检验M.进口商品检验N.出口商品检验
摘要/Summary:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

分子结构与计算化学数据展开↓

分子结构数据


 

五、分子性质数据:

1、   摩尔折射率:54.92

2、   摩尔体积(cm3/mol):210.2

3、   等张比容(90.2K):508.5

4、   表面张力(dyne/cm):34.2

5、   极化率(10-24cm3):21.77

计算化学数据


1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:8

4.可旋转化学键数量:8

5.互变异构体数量:无

6.拓扑分子极性表面积105

7.重原子数量:17

8.表面电荷:0

9.复杂度:280

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

上下游相关产品

上游产品

更多
  • 10026-04-7

    四氯硅烷

  • 108-24-7

    乙酸酐

  • 64-19-7

    乙酸

  • 540-88-5

    醋酸叔丁酯

  • 127-09-3

    无水醋酸钠

下游产品

更多
  • 3148-73-0

    N,N'-二乙酰基肼

  • 18270-02-5

    4,10-dimethyl-1,5,7,11-tetraoxa-6-silaspiro[5.5]undecane

  • 60-35-5

    乙酰胺

  • 112926-00-8

    高纯度硅胶I

  • 99-91-2

    对氯苯乙酮

立即下载安装“化学加”APP
专业、功能强大,随时调用更加方便