Plumbane, bromotriethyl-

Plumbane, bromotriethyl- 基本信息
CAS号 41141-89-3 分子式 C6H15BrPb
分子量 374.30704 精确质量  374.01235
PSA  0.00000 LogP  3.38650

基本信息 展开↓

CAS号:
41141-89-3
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分子式:
C6H15BrPb
分子量:
374.30704
英文名称:
Plumbane, bromotriethyl-
英文别名:
Plumbane, bromotriethyl-;
Lead, bromotriethyl- (7CI);
Triethyllead bromide (6CI);
Bromotriethylplumbane;
NSC 203276
精确分子量/精确质量:
374.01235
极性分子表面积/PSA:
0.00000
油水分配系数/LogP:

LogP值指的是某物质在正辛醇/水两相体系中的分配系数的对数值,反映了物质在油水两相中的分配情况。其中、LogP值越大,说明该物质越亲油;反之,LogP值越小,则说明该物质越亲水。
InChI:
The Key: RLEMIFPVSKAYPE-UHFFFAOYSA-M

物化性质展开↓

沸点:
218.8ºC at 760 mmHg
闪点:
86.2ºC

安全信息展开↓

海关代码:
2931900090

合成路线查看所有的合成路线

  • 7726-95-6

    溴素

  • +

  • 78-00-2

    4-乙酰氧基苯甲醛

  • ~30%

  • 41141-89-3

    bromo(triethyl)plumbane

  • 100-39-0

    溴化苄

  • +

  • 1067-14-7

    三乙基铅氯化物

  • 41141-89-3

    bromo(triethyl)plumbane

  • +

  • 100-44-7

    苄基氯

  • 78-00-2

    4-乙酰氧基苯甲醛

  • 41141-89-3

    bromo(triethyl)plumbane

MSDS 展开↓

    Version 1.4
    Regulation (EC) No 1907/2006

    1 - Product and Company Information

    Product Name        BROMOTRIETHYLLEAD - 50 MG    

    2 - Hazards Identification

    SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
    May cause harm to the unborn child. Also very toxic by inhalation,
    in contact with skin and if swallowed. Danger of cumulative
    effects. Very toxic to aquatic organisms, may cause long-term
    adverse effects in the aquatic environment. Possible risk of
    impaired fertility.
    Repr. Cat.1 Repr. Cat.3

    3 - Composition/Information on Ingredients

    Product Name        CAS #        EC no        Annex I    
    Index Number
    BROMOTRIETHYLLEAD        41141-89-3 None        082-002-00-1    
    Formula        C6H15BrPb    
    Molecular Weight 374,2900 AMU

    4 - First Aid Measures

    AFTER INHALATION
    If inhaled, remove to fresh air. If not breathing give
    artificial respiration. If breathing is difficult, give oxygen.
    AFTER SKIN CONTACT
    In case of skin contact, flush with copious amounts of water for
    at least 15 minutes. Remove contaminated clothing and shoes.
    Call a physician.
    AFTER EYE CONTACT
    In case of contact with eyes, flush with copious amounts of
    water for at least 15 minutes. Assure adequate flushing by
    separating the eyelids with fingers. Call a physician.
    AFTER INGESTION
    ALDRICH        www.molbase.com    
    If swallowed, wash out mouth with water provided person is
    conscious. Call a physician immediately.

    5 - Fire Fighting Measures

    EXTINGUISHING MEDIA
    Suitable: Water spray. Carbon dioxide, dry chemical powder, or
    appropriate foam.
    SPECIAL RISKS
    Specific Hazard(s): Emits toxic fumes under fire conditions.
    SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
    Wear self-contained breathing apparatus and protective clothing
    to prevent contact with skin and eyes.

    6 - Accidental Release Measures

    PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
    Evacuate area.
    PROCEDURE(S) OF PERSONAL PRECAUTION(S)
    Wear self-contained breathing apparatus, rubber boots, and heavy
    rubber gloves.
    METHODS FOR CLEANING UP
    Sweep up, place in a bag and hold for waste disposal. Avoid
    raising dust. Ventilate area and wash spill site after material
    pickup is complete.

    7 - Handling and Storage

    HANDLING
    Directions for Safe Handling: Do not breathe dust. Do not get in
    eyes, on skin, on clothing. Avoid prolonged or repeated exposure.
    STORAGE
    Conditions of Storage: Keep tightly closed.

    8 - Exposure Controls / Personal Protection

    ENGINEERING CONTROLS
    Safety shower and eye bath. Use only in a chemical fume hood.
    GENERAL HYGIENE MEASURES
    Wash contaminated clothing before reuse. Wash thoroughly after
    handling.
    PERSONAL PROTECTIVE EQUIPMENT
    Respiratory Protection: Use respirators and components tested and
    approved under appropriate government standards such as NIOSH (US)
    or CEN (EU). Where risk assessment shows air-purifying respirators
    are appropriate use a full-face particle respirator type N100 (US)
    or type P3 (EN 143) respirator cartridges as a backup to
    engineering controls. If the respirator is the sole means of
    protection, use a full-face supplied air respirator.
    Hand Protection: Compatible chemical-resistant gloves.
    Eye Protection: Chemical safety goggles.

    9 - Physical and Chemical Properties
    ALDRICH        www.molbase.com    

    Appearance        Physical State: Solid    
    Property        Value        At Temperature or Pressure    
    pH N/A
    BP/BP Range        N/A    
    MP/MP Range        N/A    
    Flash Point        N/A    
    Flammability        N/A    
    Autoignition Temp        N/A    
    Oxidizing Properties N/A
    Explosive Properties N/A
    Explosion Limits        N/A    
    Vapor Pressure        N/A    
    Partition Coefficient N/A
    Viscosity        N/A    
    Vapor Density        N/A    
    Saturated Vapor Conc. N/A
    Evaporation Rate        N/A    
    Bulk Density        N/A    
    Decomposition Temp.        N/A    
    Solvent Content        N/A    
    Water Content        N/A    
    Surface Tension        N/A    
    Conductivity        N/A    
    Miscellaneous Data        N/A    
    Solubility        N/A    

    10 - Stability and Reactivity

    STABILITY
    Stable: Stable.
    Materials to Avoid: Strong oxidizing agents, Strong acids.
    HAZARDOUS DECOMPOSITION PRODUCTS
    Hazardous Decomposition Products: Nature of decomposition products
    not known.
    HAZARDOUS POLYMERIZATION
    Hazardous Polymerization: Will not occur

    11 - Toxicological Information

    SIGNS AND SYMPTOMS OF EXPOSURE
    To the best of our knowledge, the chemical, physical, and
    toxicological properties have not been thoroughly investigated.
    Exposure can cause: Anemia. Lead salts have been reported to
    cross the placenta and to induce embryo- and feto- mortality.
    They also have teratogenic effect in some animal species. No
    teratogenic effects have been reported with exposure to
    organometallic lead compounds. Adverse effects of lead on human
    reproduction, embryonic and fetal development, and postnatal
    (e.g., mental) development have been reported. Excessive
    exposure can affect blood, nervous, and digestive systems. The
    synthesis of hemoglobin is inhibited and results in anemia. If
    left untreated, neuromuscular dysfunction, possible paralysis,
    and encephalopathy can result. Additional symptoms of
    overexposure include: joint and muscle pain, weakness of the
    extensor muscles (frequently the hand and wrist), headache,
    ALDRICH        www.molbase.com    
    dizziness, abdominal pain, diarrhea, constipation, nausea,
    vomiting, blue line on the gums, insomnia, and metallic taste.
    High body levels produce increased cerebrospinal pressure, brain
    damage, and stupor leading to coma and often death.
    ROUTE OF EXPOSURE
    Skin Contact: May cause skin irritation.
    Skin Absorption: May be fatal if absorbed through skin.
    Eye Contact: May cause eye irritation.
    Inhalation: Material may be irritating to mucous membranes and
    upper respiratory tract. May be fatal if inhaled.
    Ingestion: May be fatal if swallowed.
    TARGET ORGAN INFORMATION
    Nerves. Blood. Kidneys. Female reproductive system. Male
    reproductive system.
    CHRONIC EXPOSURE - TERATOGEN
    Result: May cause congenital malformation in the fetus.
    CHRONIC EXPOSURE - REPRODUCTIVE HAZARD
    Result: May cause reproductive disorders.
    CMR CAT.: Carc. Cat.3

    12 - Ecological Information

    No data available.

    13 - Disposal Considerations

    SUBSTANCE DISPOSAL
    Contact a licensed professional waste disposal service to dispose
    of this material. Observe all federal, state, and local
    environmental regulations.

    14 - Transport Information

    RID/ADR
    UN#: 3467
    Class: 6.1
    PG: II
    Proper Shipping Name: Organometallic compound, toxic,
    solid, n.o.s.
    IMDG
    UN#: 3467
    Class: 6.1
    PG: II
    Proper Shipping Name: Organometallic compound, toxic,
    solid, n.o.s.
    Marine Pollutant: Yes
    Severe Marine Pollutant: No
    Technical Name: Required
    IATA
    UN#: 3467
    Class: 6.1
    PG: II
    Proper Shipping Name: Organometallic compound, toxic,
    solid, n.o.s.
    ALDRICH        www.molbase.com    
    Inhalation Packing Group I: No
    Technical Name: Required

    15 - Regulatory Information

    CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
    ANNEX I INDEX NUMBER: 082-002-00-1
    NOTA: A,E, 1
    INDICATION OF DANGER: T+-N
    Very toxic. Dangerous for the environment.
    R-PHRASES: 61-26/27/28-33-50/53-62
    May cause harm to the unborn child. Also very toxic by
    inhalation, in contact with skin and if swallowed. Danger of
    cumulative effects. Very toxic to aquatic organisms, may cause
    long-term adverse effects in the aquatic environment. Possible
    risk of impaired fertility.
    S-PHRASES: 53-45-60-61
    Restricted to professional users. Attention - Avoid exposure -
    obtain special instructions before use. In case of accident or
    if you feel unwell, seek medical advice immediately (show the
    label where possible). This material and its container must be
    disposed of as hazardous waste. Avoid release to the
    environment. Refer to special instructions/safety data sheets.
    Caution: Substance not yet fully tested (EU).
    COUNTRY SPECIFIC INFORMATION
    Germany
    WGK: 3
    Self-Classification

    16 - Other Information

    WARRANTY
    The above information is believed to be correct but does not
    purport to be all inclusive and shall be used only as a guide. The
    information in this document is based on the present state of our
    knowledge and is applicable to the product with regard to
    appropriate safety precautions. It does not represent any
    guarantee of the properties of the product. Inc.,
    shall not be held liable for any damage resulting from handling or
    from contact with the above product. See reverse side of invoice
    or packing slip for additional terms and conditions of sale.
    Copyright 2010 Co. License granted to make
    unlimitedpaper copies for internal use only.
    DISCLAIMER
    For R&D use only. Not for drug, household or other uses.
    ALDRICH        www.molbase.com    


SECTION 16 - ADDITIONAL INFORMATION
N/A

海关数据查看详细

中国海关编码:2931900090

概述:
2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%
摘要/Summary:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

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